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Lactones 32 [1]: New aspects of the application of Fusarium strains to production of alkylsubstituted ɛ-lactones

Paper ID Volume ID Publish Year Pages File Format Full-Text
17873 42702 2009 8 PDF Available
Title
Lactones 32 [1]: New aspects of the application of Fusarium strains to production of alkylsubstituted ɛ-lactones
Abstract

Wild strains Fusarium oxysporum and Fusarium avenaceum were chosen among six to the Baeyer–Villiger oxidation of alkylsubstituted cyclohexanones (1a–e) to the corresponding highly enantiomerically enriched ɛ-lactones. Besides the oxidation activity, the biocatalysts were also able to the reduction of carbonyl group. Only cis-methylcyclohexanols turned out to be further transformed to lactones. Biotransformations of optically enriched ketones and alcohols were also studied to give an overall view of stereoselectivity of the enzymes involved in biocatalytic pathway.

Keywords
Fusarium oxysporum; Fusarium avenaceum; Baeyer–Villiger oxidation; ɛ-Lactones; Ketone reduction; Alcohol oxidation
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Lactones 32 [1]: New aspects of the application of Fusarium strains to production of alkylsubstituted ɛ-lactones
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Publisher
Database: Elsevier - ScienceDirect
Journal: Enzyme and Microbial Technology - Volume 45, Issue 2, 7 August 2009, Pages 156–163
Authors
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Subjects
Physical Sciences and Engineering Chemical Engineering Bioengineering
Get Full-Text Now
Don't Miss Today's Special Offer
Price was $35.95
You save - $31
Price after discount Only $4.95
100% Money Back Guarantee
Full-text PDF Download
Online Support
Any Questions? feel free to contact us