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Photocatalytic organic syntheses using a glass-milled microchip

Paper ID Volume ID Publish Year Pages File Format Full-Text
26181 43938 2016 6 PDF Available
Title
Photocatalytic organic syntheses using a glass-milled microchip
Abstract

•A glass-milled microchip is proposed for photocatalytic organic syntheses.•Oxidation and reduction reactions for aromatic compounds are demonstrated.•Imine is synthesized using a multi-step reaction.•Photocatalytic microchip can be used more than 300 times.

Photocatalytic reactions, typically known as difficult to control due to secondary reactions and involvement of multiple radicals, were demonstrated to be controlled well by optimizing the reaction time and the microchip design. The glass-milled microchip has a good resistivity for the organic solutions and withstands multiple usage more than 100 times. The oxidization and reduction reactions were demonstrated and the flow considerably improved the conversion and yield. Furthermore, an imine synthesis was demonstrated as a multi-step reaction by combination of photocatalytic oxidation and reduction reactions.

Graphical abstractA glass-milled microchip is proposed for photocatalytic organic syntheses, which could be used more than 300 times, and oxidation and reduction reactions for aromatic compounds, multi-step reaction for imine synthesis were demonstrated.Figure optionsDownload full-size imageDownload as PowerPoint slide

Keywords
Photocatalytic organic synthesis; Microchip; Nitrobenzene; Aniline; Imine
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Publisher
Database: Elsevier - ScienceDirect
Journal: Journal of Photochemistry and Photobiology A: Chemistry - Volumes 322–323, 15 May–1 June 2016, Pages 35–40
Authors
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Subjects
Physical Sciences and Engineering Chemical Engineering Bioengineering
Get Full-Text Now
Don't Miss Today's Special Offer
Price was $35.95
You save - $31
Price after discount Only $4.95
100% Money Back Guarantee
Full-text PDF Download
Online Support
Any Questions? feel free to contact us