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A rhodamine-based colorimetric and fluorescent probe for dual sensing of Cu2+ and Hg2+ ions

Paper ID Volume ID Publish Year Pages File Format Full-Text
26206 43940 2016 7 PDF Available
Title
A rhodamine-based colorimetric and fluorescent probe for dual sensing of Cu2+ and Hg2+ ions
Abstract

•Synthesis and characterization of ‘RhAsP’.•The spectroscopic studies were carried out for investigating the selectivity of ‘RhAsP’ toward Hg2+.•Addition of mercury ion into ethanol–water solution of sensor caused a strong fluorescent emission at 586 nm.•The limit of detection was found to be 150 nM for Hg2+.

A fluorescent sensor ‘RhAsP’ prepared from rhodamine hydrazine and 2-hydroxy-acetophenone was designed and synthesised. The characterisation of ‘RhAsP’ was also accomplished by using FT-IR, 1H NMR, 13C NMR, ESI-MS, elemental analysis, fluorescence and UV/vis spectroscopy. For the purpose of investigating optical sensing behaviour of ‘RhAsP’ toward various metal ions including alkali, alkaline earth and transition metal ions (Na+, K+, Ag+, Ca2+, Mg2+, Cr3+, Fe3+, Hg2+, Cu2+, Pb2+, Zn2+, Fe2+, Co2+, Ni2+, Cd2+, Al3+ and Mn2+) in aqueous medium under physiological pH conditions, fluorescence and absorption spectroscopic techniques were carefully conducted. Thereby, ‘RhAsP’ showed both colorimetric and fluorometric selective recognition of Hg2+ from colorless to purple with a reversible ‘off–on’ fluorescence response. In addition, a nearly 100-fold increase in emission intensity was determined upon the addition of two equivalents Hg2+ ions.

Graphical abstractA highly selective and sensitive ‘off–on’ fluorescent sensor RhAsP based on rhodamine derivative for the detection of Hg2+ and Cu2+ in aqueous medium.Figure optionsDownload full-size imageDownload as PowerPoint slide

Keywords
Chemosensor; Selective; Rhodamine; Fluorometric; Hg2+ and Cu2+
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A rhodamine-based colorimetric and fluorescent probe for dual sensing of Cu2+ and Hg2+ ions
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Publisher
Database: Elsevier - ScienceDirect
Journal: Journal of Photochemistry and Photobiology A: Chemistry - Volume 318, 1 March 2016, Pages 7–13
Authors
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Subjects
Physical Sciences and Engineering Chemical Engineering Bioengineering
Get Full-Text Now
Don't Miss Today's Special Offer
Price was $35.95
You save - $31
Price after discount Only $4.95
100% Money Back Guarantee
Full-text PDF Download
Online Support
Any Questions? feel free to contact us