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Preparation and characterization of ZnO–SiO2 thin films as highly efficient photocatalyst

Paper ID Volume ID Publish Year Pages File Format Full-Text
26310 43946 2014 10 PDF Available
Title
Preparation and characterization of ZnO–SiO2 thin films as highly efficient photocatalyst
Abstract

•ZnO doped SiO2 films annealing at different temperatures were prepared.•ZnO/SiO2 films were evaluated by the determination of their photonic efficiencies.•The XRD patterns showed that the hexagonal wurtzite structure of ZnO was formed.•TEM images of ZnO nanoparticles are nearly spherical ∼5–20 nm.•10% ZnO–SiO2 annealing at 600 °C showing the highest photocatalytic activity.

ZnO doped SiO2 thin films were prepared by the sol–gel method and annealed at different temperatures from 200 to 1100 °C. SiO2 matrix is selected as support due to their high flexibility, thermal stability and high porosity and surface areas. The XRD patterns showed that the hexagonal wurtzite structure of the ZnO film was formed for all the prepared samples. TEM images of ZnO synthesized nanoparticles are almost spherical with a relatively narrow size distribution in the range of 5–20 nm according to the annealing temperature. These images clearly show the (0 0 0 1) atomic planes (interplanner distance is 0.52 nm) perpendicular to the c-axis, thus indicating that (0 0 0 1) is the preferred growth direction of these wurtzite-type ZnO. The newly prepared photocatalysts ZnO–SiO2 films have been evaluated by the determination of their photonic efficiencies for degradation of methylene blue. The photonic efficiencies of 10 wt% ZnO–SiO2 increase from 0.9 to 2.3% with increasing annealing temperature from 200 to 600 °C and then gradually decrease to 1.56% at 1100 °C. The results indicate that 10 wt% ZnO–SiO2 annealed at 600 °C showed the highest photocatalytic activity for the MB photodegradation. Our work demonstrates the ability to reduce the working temperature as well as to increase the response of ZnO thin film as a highly efficient photocatalyst, which would be of great merit for commercialized applications.

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Keywords
ZnO–SiO2; Films; Sol–gel; Photocatlyst; Photonic efficiency
First Page Preview
Preparation and characterization of ZnO–SiO2 thin films as highly efficient photocatalyst
Publisher
Database: Elsevier - ScienceDirect
Journal: Journal of Photochemistry and Photobiology A: Chemistry - Volume 275, 1 February 2014, Pages 37–46
Authors
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Subjects
Physical Sciences and Engineering Chemical Engineering Bioengineering