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Remarkable accelerating and decelerating effects of the bases on CO2 reduction using a ruthenium NADH model complex

Paper ID Volume ID Publish Year Pages File Format Full-Text
26479 43954 2015 5 PDF Available
Title
Remarkable accelerating and decelerating effects of the bases on CO2 reduction using a ruthenium NADH model complex
Abstract

•We report the organic hydride transfer reaction converting CO2 to HCO2–.•The NADH-type complex shows CO2 reduction ability by the association of the bases.•The drastic differences in the CO2 reduction rates are observed by changing the bases.•The base adduct is the key compound in the CO2 reduction.•Full characterization of the base adduct is reported.

Successful control over the rate of the organic hydride transfer reaction converting carbon dioxide to formate using a ruthenium NADH model complex, [Ru(bpy)2(pbnHH)](PF6)2 (bpy = 2,2′-bipyridine, pbnHH = 2-(pyridin-2-yl)-5,10-dihydrobenzo[b][1,5]naphthyridine) has been accomplished by the tuning of the basicity of the bases. The base adduct being found to be the key compound in the carbon dioxide reduction has been fully characterized through various physicochemical methods.

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Keywords
Ruthenium complex; NAD model ligands; Carbon dioxide reduction; Organic hydride; transfer
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Remarkable accelerating and decelerating effects of the bases on CO2 reduction using a ruthenium NADH model complex
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Publisher
Database: Elsevier - ScienceDirect
Journal: Journal of Photochemistry and Photobiology A: Chemistry - Volume 313, 1 December 2015, Pages 163–167
Authors
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Subjects
Physical Sciences and Engineering Chemical Engineering Bioengineering
Get Full-Text Now
Don't Miss Today's Special Offer
Price was $35.95
You save - $31
Price after discount Only $4.95
100% Money Back Guarantee
Full-text PDF Download
Online Support
Any Questions? feel free to contact us