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Efficient refinement of a metal–organic framework MIL-53(Fe) by UV–vis irradiation in aqueous hydrogen peroxide solution

Paper ID Volume ID Publish Year Pages File Format Full-Text
26543 43961 2014 5 PDF Available
Title
Efficient refinement of a metal–organic framework MIL-53(Fe) by UV–vis irradiation in aqueous hydrogen peroxide solution
Abstract

In analogy to photocatalytic materials, the metal–organic framework MIL-53(Fe) showed up self-cleaning ability under light. In the presence of hydrogen peroxide and with exposure under UVA–vis irradiation, organic impurities were decomposed completely without damage of MIL-53(Fe) structure. The method is efficient and environment-friendly such that all the free and confined 1,4-benzenedicarboxylic acid in the MOF were decomposed within 1 h at room temperature. The MIL-53(Fe) samples before and after purification were fully analyzed using XRD, FTIR, FE-SEM and TGA measurements.

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Keywords
Microporous materials; Self-cleaning ability; Photocatalyst; Metal–organic frameworks; Purification; UV–vis irradiation
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Efficient refinement of a metal–organic framework MIL-53(Fe) by UV–vis irradiation in aqueous hydrogen peroxide solution
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Publisher
Database: Elsevier - ScienceDirect
Journal: Journal of Photochemistry and Photobiology A: Chemistry - Volume 288, 15 August 2014, Pages 55–59
Authors
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Subjects
Physical Sciences and Engineering Chemical Engineering Bioengineering
Get Full-Text Now
Don't Miss Today's Special Offer
Price was $35.95
You save - $31
Price after discount Only $4.95
100% Money Back Guarantee
Full-text PDF Download
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Any Questions? feel free to contact us