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Room temperature aqueous solution synthesis of pinacol (C6) by photocatalytic CC coupling of isopropanol

Paper ID Volume ID Publish Year Pages File Format Full-Text
26809 43980 2013 5 PDF Available
Title
Room temperature aqueous solution synthesis of pinacol (C6) by photocatalytic CC coupling of isopropanol
Abstract

•Preparation of aliphatic pinacol for the first time in an aqueous solution at room temperature.•Photocatalytic CC coupling reaction using isopropanol as the starting material.•Phase and pore structure modulation of commercial TiO2 by calcination.

Aliphatic pinacol (C6) was prepared for the first time by photocatalytic CC coupling of isopropanol in an aqueous solution at room temperature by using Pt/TiO2 catalyst. The phase and pore structure of TiO2 was modulated by calcination of the commercial TiO2 at 500–900 °C. High isopropanol conversion was achieved when the commercial P25 TiO2 was calcined at 600 °C for 20 h, and the highest pinacol yield was of 14.7% at the photocatalytic reaction of 20 h.

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Keywords
Photocatalysis; CC coupling reaction; Pinacol; Titania; Structure modulation; Calcination
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Room temperature aqueous solution synthesis of pinacol (C6) by photocatalytic CC coupling of isopropanol
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Publisher
Database: Elsevier - ScienceDirect
Journal: Journal of Photochemistry and Photobiology A: Chemistry - Volume 272, 15 November 2013, Pages 1–5
Authors
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Subjects
Physical Sciences and Engineering Chemical Engineering Bioengineering
Get Full-Text Now
Don't Miss Today's Special Offer
Price was $35.95
You save - $31
Price after discount Only $4.95
100% Money Back Guarantee
Full-text PDF Download
Online Support
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