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Fluorescence detection of iodide anion using a donor–acceptor (D–A) thiourea derivative

Paper ID Volume ID Publish Year Pages File Format Full-Text
26863 43982 2014 7 PDF Available
Title
Fluorescence detection of iodide anion using a donor–acceptor (D–A) thiourea derivative
Abstract

•One simple structure probe based on thiourea moiety was developed successfully.•I− can be discriminated according to the fluorescence quenching in THF/water (v/v = 9/1) Tris–HCl buffer solution.•The probe is applied to determine iodide in powdered milk and urine samples, and the result is satisfactory.•The mechanism of the fluorescence quenching is supported by quantum chemical calculation, UV and 1H NMR titration.

1-(4-acetyl-phenyl)-3-(4-N,N-dimethylaminophenyl)-thiourea is synthesized and characterized by NMR, IR, MS and elemental analysis. The probe exhibits the “turn-off” fluorescence response to iodide anion in THF/H2O (v/v = 9/1) pH = 7.4 Tris–HCl buffer solution, which is attributed to the intramolecular charge transfer (ICT). It is found that the probe has a detection limit of 0.336 μM. Such interesting results could be further supported by quantum chemical calculation, UV and 1H NMR titration. Moreover, the probe is applied to determine iodide in powdered milk and urine samples. This experiment shows a good agreement between added and detected concentration of the iodide in real samples.

Keywords
Donor–acceptor (D–A) thiourea; Fluorescence recognition; Iodide anion; Intramolecular charge transfer
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Fluorescence detection of iodide anion using a donor–acceptor (D–A) thiourea derivative
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Publisher
Database: Elsevier - ScienceDirect
Journal: Journal of Photochemistry and Photobiology A: Chemistry - Volume 292, 15 October 2014, Pages 49–55
Authors
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Subjects
Physical Sciences and Engineering Chemical Engineering Bioengineering
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Price was $35.95
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