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Chalcone derivatives as fluorescence turn-on chemosensors for cyanide anions

Paper ID Volume ID Publish Year Pages File Format Full-Text
26929 43987 2012 6 PDF Available
Title
Chalcone derivatives as fluorescence turn-on chemosensors for cyanide anions
Abstract

Three o-hydroxy chalcone derivatives 1–3 with carbazolyl (1), pyrene (2) and 4-nitrobenzene (3) as terminal group have been synthesized. Their crystal structures, photophysical properties in CH3CN and recognition properties for cyanide anions have also been examined. The research indicates that the stronger electroaffinity of the chalcone derivative's β-unit is beneficial to Michael reaction and can improve the response rate of the compound to cyanide anions. These compounds are found to be able to recognize cyanide anions with fluorescence turn-on response. Especially, compound 3 with strong electron accepting group exhibits remarkable response to cyanide anions in CH3CNH2O (1:1, v/v) solution with a ca. 40-fold intensity enhancement.

Graphical abstractThree o-hydroxy chalcone derivatives with carbazolyl (1), pyrene (2) and 4-nitrobenzene (3) as terminal group have been synthesized, which exhibit remarkable response to cyanide anions. Compound 3 can recognize cyanide anions with fluorescence turn-on response in CH3CNH2O (1:1, v/v) solution.Figure optionsDownload full-size imageDownload as PowerPoint slideHighlights► Three o-hydroxy chalcone derivatives were synthesized. ► The compounds can recognize cyanide anions with fluorescence turn-on response. ► The compound containing nitro group can recognize cyanides in aqueous solution.

Keywords
Chalcone derivative; Cyanide anion; Chemosensor; Turn-on fluorescence; Michael acceptor; Crystal structure
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Chalcone derivatives as fluorescence turn-on chemosensors for cyanide anions
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Publisher
Database: Elsevier - ScienceDirect
Journal: Journal of Photochemistry and Photobiology A: Chemistry - Volume 244, 15 September 2012, Pages 65–70
Authors
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Subjects
Physical Sciences and Engineering Chemical Engineering Bioengineering
Get Full-Text Now
Don't Miss Today's Special Offer
Price was $35.95
You save - $31
Price after discount Only $4.95
100% Money Back Guarantee
Full-text PDF Download
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