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Tunable molecular configuration for significant enhancement of two-photon absorption based on novel octupolar benzoimidazole derivatives

Paper ID Volume ID Publish Year Pages File Format Full-Text
26935 43988 2014 9 PDF Available
Title
Tunable molecular configuration for significant enhancement of two-photon absorption based on novel octupolar benzoimidazole derivatives
Abstract

•Two novel ctupolar molecules including benzoimidazole D–A derivatives were synthesized and characterized.•Both of them have the same D, A and π-conjugating units with only the different molecular configuration.•Their two-photon absorption (2PA) and charge transfer performance are studied.•Interestingly, the 2PA response of them differs by almost three times.

Two novel octupolar molecules including benzoimidazole electron-accepting (A) branches and a triphenylamine electron-donating (D) center have been synthesized and characterized (p-ETBN and m-ETBN). Their photophysical and photochemical properties were investigated systematically including single-photon absorption, two-photon absorption (2PA) and charge transfer performance. Their 2PA properties have been investigated by the open aperture Z-scan technique, and the values of the 2PA cross section at 800 nm for p-ETBN and m-ETBN are ∼300 GM and ∼100 GM, respectively. Interestingly, both of them have the same D, A and π-conjugating units with only the different molecular configuration, the 2PA response of them differs by almost three times, which are found to be the different excited-state dipole moments and intramolecular charge-transfer. Our results reveal a new rule of molecular design for obtaining some excellent 2PA materials for their potential biophotonic and optoelectronic applications.

Keywords
Molecular configuration; Two-photon absorption; Charge transfer performance; Excited-state dipoles
First Page Preview
Tunable molecular configuration for significant enhancement of two-photon absorption based on novel octupolar benzoimidazole derivatives
Publisher
Database: Elsevier - ScienceDirect
Journal: Journal of Photochemistry and Photobiology A: Chemistry - Volume 290, 15 September 2014, Pages 22–30
Authors
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Subjects
Physical Sciences and Engineering Chemical Engineering Bioengineering