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Deprotonation and chelation synergically triggered near infrared fluorescence for selective detection of Hg(II)

Paper ID Volume ID Publish Year Pages File Format Full-Text
26941 43988 2014 5 PDF Available
Title
Deprotonation and chelation synergically triggered near infrared fluorescence for selective detection of Hg(II)
Abstract

•A NIR fluorescence turn-on probe for Hg (II) was designed and synthesized.•Chelation and deprotonation synergically triggered a NIR emission.•The probe exhibited Hg (II)-specific fluorescence response.

A convenient strategy that does not need the tedious modification of the π-conjugation moiety to construct near infrared (NIR) sensors is in high demand. In this study, we present the design and synthesis of a NIR Hg(II) turn-on fluorescent sensor BODIPY-SAN, which shows several advantages including (1) simple to be synthesized by only a predictable modification of the core structure of 6-hydroxyindole-based BODIPY, (2) giving a turn-on NIR emission synergically triggered by chelation and deprotonation, (3) exhibiting Hg(II)-specific fluorescence response with the detection limit to be 5 × 10−7 M, (4) functioning as a novel cell-permeable NIR probe for intracellular Hg(II) in living HeLa cells.

Graphical abstractA NIR fluorescence turn-on probe shows impressively high selectivity toward Hg (II), which is triggered by the synergical effect of chelation and deprotonation upon binding to Hg (II).Figure optionsDownload full-size imageDownload as PowerPoint slide

Keywords
NIR sensor; Synergical effect; Turn-on; Hg(II); Living cells
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Deprotonation and chelation synergically triggered near infrared fluorescence for selective detection of Hg(II)
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Publisher
Database: Elsevier - ScienceDirect
Journal: Journal of Photochemistry and Photobiology A: Chemistry - Volume 290, 15 September 2014, Pages 72–76
Authors
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Subjects
Physical Sciences and Engineering Chemical Engineering Bioengineering
Get Full-Text Now
Don't Miss Today's Special Offer
Price was $35.95
You save - $31
Price after discount Only $4.95
100% Money Back Guarantee
Full-text PDF Download
Online Support
Any Questions? feel free to contact us