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Elimination of estrogen and its estrogenicity by heterogeneous photo-Fenton catalyst β-FeOOH/resin

Paper ID Volume ID Publish Year Pages File Format Full-Text
26975 43991 2010 7 PDF Available
Title
Elimination of estrogen and its estrogenicity by heterogeneous photo-Fenton catalyst β-FeOOH/resin
Abstract

β-FeOOH loaded resin (β-FeOOH/resin) was synthesized through in situ hydrolysis of Fe(III)-exchanged resin and its physiochemical properties were characterized. The typical environmental endocrine disruptor, natural hormone 17β-estradiol (E2) was removed by heterogeneous photo-Fenton reaction in presence of β-FeOOH/resin and H2O2 under weak UV irradiation. E2 degradation was effectively achieved by hydroxyl radicals that were generated in the heterogeneous photo-Fenton process. pH was an important factor that affected efficiency of E2 degradation and catalyst's surface activity which were determined by X-ray photoelectron spectrum (XPS). The mechanical stability and photo activity of β-FeOOH/resin were tested by several cycles of photo catalytic degradation and FTIR. The reduction of estrogenicity of E2 would be very important to the safety of treated water so as to avoid secondary pollution. It seems that the heterogeneous Fenton oxidation would be a promising method to eliminate the steroid estrogenic compounds.

Keywords
Heterogeneous Fenton reaction; β-FeOOH; 17β-Estradiol; Estrogenicity
First Page Preview
Elimination of estrogen and its estrogenicity by heterogeneous photo-Fenton catalyst β-FeOOH/resin
Publisher
Database: Elsevier - ScienceDirect
Journal: Journal of Photochemistry and Photobiology A: Chemistry - Volume 212, Issues 2–3, 20 May 2010, Pages 94–100
Authors
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Subjects
Physical Sciences and Engineering Chemical Engineering Bioengineering