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Participation of a heterolytic path in the photochemistry of chlorobenzene

Paper ID Volume ID Publish Year Pages File Format Full-Text
27037 43996 2010 5 PDF Available
Title
Participation of a heterolytic path in the photochemistry of chlorobenzene
Abstract

The photochemistry of chlorobenzene in different media has been studied in the presence of oxygen as well as of allyltrimethylsilane and benzene. These are selective traps of the phenyl radical and of the phenyl cation, respectively. Photo-homolysis is a primary process, under most conditions the main processes. However, in an acidic alcohol such as 2,2,2-trifluoroethanol (TFE), this is substituted by photoheterolysis, though with a lower efficiency.

Keywords
Photoheterolysis; Dehalogenation; Aryl halides; Chlorobenzene; Phenyl cation
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Participation of a heterolytic path in the photochemistry of chlorobenzene
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Publisher
Database: Elsevier - ScienceDirect
Journal: Journal of Photochemistry and Photobiology A: Chemistry - Volume 210, Issues 2–3, 25 February 2010, Pages 140–144
Authors
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Subjects
Physical Sciences and Engineering Chemical Engineering Bioengineering
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Price was $35.95
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