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Phototransformations of some 3-alkoxy-6-chloro-2-{(E)-1′-methyl-2′-phenylvinyl}chromones: A study of type-II and triene bichromophoric system

Paper ID Volume ID Publish Year Pages File Format Full-Text
27439 44023 2009 7 PDF Available
Title
Phototransformations of some 3-alkoxy-6-chloro-2-{(E)-1′-methyl-2′-phenylvinyl}chromones: A study of type-II and triene bichromophoric system
Abstract

Irradiation of a methanolic solution of 3-alkoxy-6-chloro-2-{(E)-1′-methyl-2′-phenylvinyl}-4-oxo-4H-1-benzopyrans yielded 12H-benzo[a]xanthen-12-one, pyranopyrones, oxetanopyrananones and 7-chloro-3-methyl-2-phenyl-1,4-dioxa-cyclopenta-[b]naphthalene-9-one depending upon the structure of 3-alkoxy group (methoxy, benzyloxy, and allyloxy). The methyl group on the styryl moiety has been found to have a profound effect on the product formation due to the variation of energy gap between the π–π* excited state of triene system as compared to the n–π* state of the CO group.

Keywords
1,4-Biradical; Pyranopyrone; Photocyclisation; 12H-Benzo(a)xanthen-12-one
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Phototransformations of some 3-alkoxy-6-chloro-2-{(E)-1′-methyl-2′-phenylvinyl}chromones: A study of type-II and triene bichromophoric system
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Publisher
Database: Elsevier - ScienceDirect
Journal: Journal of Photochemistry and Photobiology A: Chemistry - Volume 204, Issues 2–3, 20 May 2009, Pages 122–128
Authors
, , , , ,
Subjects
Physical Sciences and Engineering Chemical Engineering Bioengineering
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Price was $35.95
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