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Multicationic monomethine dyes as sensitizers in two- and three-component photoinitiating systems for multiacrylate monomers

Paper ID Volume ID Publish Year Pages File Format Full-Text
27522 44028 2010 12 PDF Available
Title
Multicationic monomethine dyes as sensitizers in two- and three-component photoinitiating systems for multiacrylate monomers
Abstract

This paper is focused on the description of the synthesis, spectroscopic and electrochemical properties, and the free radical photoinitiation abilities of new multi-cationic monomethine dyes.The new monomethine dyes were employed both as the visible light photoinitiators of acrylate monomer polymerization and as fluorescence probes for monitoring the progress of polymerization. A degree of polymer cure from the measurement of the changes in the probe emission intensity and position shift during the thermally initiated polymerization of monoacrylate was obtained. A distinct increase in the intensity of the dyes fluorescence was observed during polymerization when the degree of monomer conversion was gradually increasing.The second part of this work is the possibility of an application of the dyes synthesized in combination with borate anions, as photoinitiating systems.Novel multi-cationic monomethine dyes paired with n-butyltriphenylborate anions are very efficient visible light photoinitiators of free radical polymerization of acrylate monomers. Their photoinitiating abilities were compared with the photoinitiation ability of Rose Bengal derivative, e.g. typical triplet state photoinitiator.The addition of a second co-initiator to the two-component photoinitiating system (monomethine borate salts) enhances their photoinitiating abilities.

Keywords
Dyes; Fluorescence probes; Initiating systems; Free radical polymerization
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Multicationic monomethine dyes as sensitizers in two- and three-component photoinitiating systems for multiacrylate monomers
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Publisher
Database: Elsevier - ScienceDirect
Journal: Journal of Photochemistry and Photobiology A: Chemistry - Volume 214, Issue 1, 5 July 2010, Pages 74–85
Authors
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Subjects
Physical Sciences and Engineering Chemical Engineering Bioengineering
Get Full-Text Now
Don't Miss Today's Special Offer
Price was $35.95
You save - $31
Price after discount Only $4.95
100% Money Back Guarantee
Full-text PDF Download
Online Support
Any Questions? feel free to contact us