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Synthesis and properties of novel chemiluminescent biological probes: 2- and 3-(2-Succinimidyloxycarbonylethyl)phenyl acridinium esters

Paper ID Volume ID Publish Year Pages File Format Full-Text
27853 44046 2009 8 PDF Available
Title
Synthesis and properties of novel chemiluminescent biological probes: 2- and 3-(2-Succinimidyloxycarbonylethyl)phenyl acridinium esters
Abstract

Five new chemiluminescent aryl acridiniumcarboxylate esters 6–10, with a linker group in an ortho- or meta-position of the phenoxy ring, have been synthesized. The ortho- derivatives 6, 7 and 9 show significant improvement in the quantum yield of chemiluminescence and slower chemiluminescence kinetics compared to the unsubstituted para- derivative, 1, while the ortho- derivative 8 shows quicker chemiluminescence kinetics and a lower quantum yield of chemiluminescence. The meta- derivative 10 shows similar chemiluminescent properties to that of its para-substituted analogue.

Keywords
Acridinium ester; Chemiluminescence; Chemiluminescence immunoassay
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Synthesis and properties of novel chemiluminescent biological probes: 2- and 3-(2-Succinimidyloxycarbonylethyl)phenyl acridinium esters
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Publisher
Database: Elsevier - ScienceDirect
Journal: Journal of Photochemistry and Photobiology A: Chemistry - Volume 203, Issue 1, 5 March 2009, Pages 72–79
Authors
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Subjects
Physical Sciences and Engineering Chemical Engineering Bioengineering
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Price was $35.95
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Price after discount Only $4.95
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