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Phosphorescence properties and chiral discrimination of camphorquinone enantiomers in the presence of α-cyclodextrin and 1,2-dibromoethane

Paper ID Volume ID Publish Year Pages File Format Full-Text
27927 44050 2010 7 PDF Available
Title
Phosphorescence properties and chiral discrimination of camphorquinone enantiomers in the presence of α-cyclodextrin and 1,2-dibromoethane
Abstract

Strong room temperature phosphorescence (RTP) of camphorquinone (CQ) is synergistically induced by α-cyclodextrin (α-CD) and 1,2-dibromoethane (1,2-DBE) without removal of oxygen dissolved in the solution because of the formation of ternary complex of α-CD, CQ, and 1,2-DBE. Both (R)-CQ and (S)-CQ exhibit single exponential phosphorescence decay with lifetimes of (0.274 ± 0.014) and (0.639 ± 0.021) ms for (R)-CQ and (S)-CQ, respectively. The relatively large RTP lifetime difference observed for (R)-CQ and (S)-CQ enables easy spectroscopic discrimination between this pair of enantiomers. The apparent association constant of (S)-CQ/1,2-DBE/α-CD complex is larger than that of (R)-CQ/1,2-DBE/α-CD complex, implying that the former ternary complex should consist of an optimal arrangement of components. 1H NMR as well as 2D NMR spectroscopy has been used to study the inclusion complexation of α-cyclodextrin with CQ in order to understand the binding model.

Keywords
Camphorquinone; Room temperature phosphorescence; Lifetime; Chiral discrimination
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Phosphorescence properties and chiral discrimination of camphorquinone enantiomers in the presence of α-cyclodextrin and 1,2-dibromoethane
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Publisher
Database: Elsevier - ScienceDirect
Journal: Journal of Photochemistry and Photobiology A: Chemistry - Volume 212, Issue 1, 30 April 2010, Pages 49–55
Authors
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Subjects
Physical Sciences and Engineering Chemical Engineering Bioengineering
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Price was $35.95
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