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Molecular recognition of anthracene and indeno-pyridine by (dibenzoylmethanato)boron difluoride in ethanol

Paper ID Volume ID Publish Year Pages File Format Full-Text
27985 44054 2012 8 PDF Available
Title
Molecular recognition of anthracene and indeno-pyridine by (dibenzoylmethanato)boron difluoride in ethanol
Abstract

Electron-deficient (dibenzoylmethanato)boron difluoride (DBMBF2) can efficiently discriminate between electron-rich polynuclear aromatic hydrocarbons like naphthalene (A1), anthracene (A2) or phenanthrene (A3). Even using the same sort of electron donor–acceptor (EDA) interaction, DBMBF2, can recognise different polar polynuclear aromatic systems containing indeno-pyridine groups (I1–I3). EDA Interaction has been studied both in the ground and excited states for all the six interacting systems (A, I). In all cases, absorption isosbestic has been established, but DBMBF2 forms iso-emissive complexes only with A1, A3, I1 and I3. Ground state association constants for all the complexes are varied widely. Anthracene (A2) and indeno-pyridine (I2) can be discriminated easily with their high binding constants. Theoretical justification for complex formations in terms of geometry, heat of formation, charge distribution and HOMO–LUMO interactions are provided on the basis of DFT calculations.

► (Dibenzoylmethanato)boron difluoride is good binder of electron-rich poly-aromatic systems in the ground state. ► It forms ground state isosbestic with naphthalene, anthracene and phenanthrene like poly-aromatic hydrocarbons and with three indeno-pyridine systems. ► Their excited states are more loosely bound compared to the ground state. ► No excited state isosbestic are formed with anthracene and/or indeno-pyridine. ► Stabilisations of these complexes are the determining factors for this interaction.

Keywords
Isosbestic formation; Anthracene and indeno-pyridine recognition; Isoemissive complex; (Dibenzoylmethanato)boron difluoride; DFT/MPW1PW91 calculation
First Page Preview
Molecular recognition of anthracene and indeno-pyridine by (dibenzoylmethanato)boron difluoride in ethanol
Publisher
Database: Elsevier - ScienceDirect
Journal: Journal of Photochemistry and Photobiology A: Chemistry - Volume 248, 15 November 2012, Pages 55–62
Authors
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Subjects
Physical Sciences and Engineering Chemical Engineering Bioengineering