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Methylene blue–calixarenesulfonate supramolecular complexes and aggregates in aqueous solutions

Paper ID Volume ID Publish Year Pages File Format Full-Text
28060 44058 2009 6 PDF Available
Title
Methylene blue–calixarenesulfonate supramolecular complexes and aggregates in aqueous solutions
Abstract

The complexation of methylene blue (MB) by calix[n]arenesulfonates (SCAn, n = 4, 6, 8) was studied in aqueous solutions with various ionic strengths, using absorption and fluorescence spectroscopy and laser flash photolysis. The simultaneous reactions MB + SCAn ↔ MB·SCAn (1) and MB·SCAn + MB ↔ MB2·SCAn (2) were observed. The equilibrium constants K(1) and K(2) are high (105–107), their dependence on the ionic strength can be described by the extended Debye–Hückel law. K(2) > K(1) for all the three systems, in accord with the strongly aggregating nature of MB. In MB–SCA8 mixtures complexes with more than two MB units were also detected. The fluorescence of the dye is partially or completely quenched in the complexes, the formation of triplet state complexed MB cations is negligible. At low SCAn concentrations and ionic strengths the formation of colloidal aggregates was detected by resonance Rayleigh scattering.

Keywords
Calixarene; Supramolecular complex; Aggregation; Fluorescence quantum yield; Triplet lifetime; Electron transfer
First Page Preview
Methylene blue–calixarenesulfonate supramolecular complexes and aggregates in aqueous solutions
Publisher
Database: Elsevier - ScienceDirect
Journal: Journal of Photochemistry and Photobiology A: Chemistry - Volume 207, Issues 2–3, 25 September 2009, Pages 167–172
Authors
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Subjects
Physical Sciences and Engineering Chemical Engineering Bioengineering