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Solid-state chiral optical properties of axially chiral binaphthyl acid derivatives

Paper ID Volume ID Publish Year Pages File Format Full-Text
28764 44090 2011 5 PDF Available
Title
Solid-state chiral optical properties of axially chiral binaphthyl acid derivatives
Abstract

It is important to first determine the solid-state chiral optical properties of basic fluorescence supramolecular building blocks that can form a network structure via intermolecular interactions. Although the circularly polarized luminescence (CPL) properties of (R)-1,1′-binaphthyl-2,2′-dicarboxylic acid with axial chirality could not be measured in either the solution or solid states, those of (R)-1,1′-binaphthyl-2,2′-diyl hydrogen phosphate with axial chirality were successfully measured in both states. The solid-state CPL originates from the intramolecular interaction of single molecule, rather than intermolecular interactions in the crystal.

► We successfully observed the CPL of 1,1′-binaphthyl-2,2′-diyl hydrogen phosphate in the solid pellet, film, and solution states.

Keywords
Axial chirality; Binaphthyl; Circular dichroism (CD); Circularly polarized luminescence (CPL); Fluorescence
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Solid-state chiral optical properties of axially chiral binaphthyl acid derivatives
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Publisher
Database: Elsevier - ScienceDirect
Journal: Journal of Photochemistry and Photobiology A: Chemistry - Volume 220, Issues 2–3, 20 May 2011, Pages 134–138
Authors
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Subjects
Physical Sciences and Engineering Chemical Engineering Bioengineering
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