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Photophysical studies of 7-hydroxy-4-methyl-8-(4′-methylpiperazin-1′-yl) methylcoumarin: A new fluorescent chemosensor for zinc and nickel ions in water

Paper ID Volume ID Publish Year Pages File Format Full-Text
28839 44096 2006 6 PDF Available
Title
Photophysical studies of 7-hydroxy-4-methyl-8-(4′-methylpiperazin-1′-yl) methylcoumarin: A new fluorescent chemosensor for zinc and nickel ions in water
Abstract

The title compound, a new coumarin based fluorophore having a piperazine moiety as the photoinduced electron transfer (PET) switch was prepared and its photophysical properties studied in various solvents and under different pH. Solvatochromic shift in the fluorescence spectrum revealed an increase in the dipole moment in the lowest excited singlet state compared to that in the ground state. The compound also showed an interesting intramolecular photoinduced proton transfer phenomenon in the excited state under neutral pH. It was effectively utilized as a new Chelation-enhanced fluorescence (CHEF) based chemosensor for zinc and nickel ions in water.

Keywords
Chemosensor; Coumarin; Intramolecular proton transfer; Solvatochromic shift; Chelation-enhanced fluorescence
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Photophysical studies of 7-hydroxy-4-methyl-8-(4′-methylpiperazin-1′-yl) methylcoumarin: A new fluorescent chemosensor for zinc and nickel ions in water
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Publisher
Database: Elsevier - ScienceDirect
Journal: Journal of Photochemistry and Photobiology A: Chemistry - Volume 177, Issue 1, 1 January 2006, Pages 55–60
Authors
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Subjects
Physical Sciences and Engineering Chemical Engineering Bioengineering
Get Full-Text Now
Don't Miss Today's Special Offer
Price was $35.95
You save - $31
Price after discount Only $4.95
100% Money Back Guarantee
Full-text PDF Download
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Any Questions? feel free to contact us