fulltext.study @t Gmail

New NIR-emitting complexes of platinum(II) and palladium(II) with fluorinated benzoporphyrins

Paper ID Volume ID Publish Year Pages File Format Full-Text
28955 44109 2009 8 PDF Available
Title
New NIR-emitting complexes of platinum(II) and palladium(II) with fluorinated benzoporphyrins
Abstract

New platinum(II) and palladium(II) complexes with fluorinated benzoporphyrins are prepared and characterized. The photo-physical and electrochemical properties, as well as quenching by oxygen are investigated. The complexes possess highly efficient room-temperature NIR phosphorescence and are excitable with blue- and red-light. The fluorinated derivatives show improved photo-physical properties and photo-stability. The new dyes are particularly suitable as indicators for the use in optical oxygen sensors.

Keywords
Benzoporphyrin; Phosphorescence; Metal complex; Oxygen quenching
First Page Preview
New NIR-emitting complexes of platinum(II) and palladium(II) with fluorinated benzoporphyrins
Publisher
Database: Elsevier - ScienceDirect
Journal: Journal of Photochemistry and Photobiology A: Chemistry - Volume 201, Issues 2–3, 25 January 2009, Pages 128–135
Authors
, , , , , ,
Subjects
Physical Sciences and Engineering Chemical Engineering Bioengineering