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Photoreactive inclusion complex of aryliodonium salt encapsulated by methylated-β-cyclodextrin

Paper ID Volume ID Publish Year Pages File Format Full-Text
29139 44124 2008 7 PDF Available
Title
Photoreactive inclusion complex of aryliodonium salt encapsulated by methylated-β-cyclodextrin
Abstract

A novel photoreactive inclusion complex (PIC) with an excellent water solubility was obtained by the complexation of methylated-β-cyclodextrin (Me-β-CD) with the hydrophobic 4,4′-dimethyl diphenyliodonium salt (DMDPI). The photoreactivity of the complex PIC was examined by the kinetic studies in order to evaluate the influence of Me-β-CD complexation. The photoreactive rate was enhanced in the photolysis of PIC compared with the uncomplexed DMDPI. By employing the photosensitizer at the visible region composed with PIC, the complex system can be used to initiate the photoreaction even in the visible region.

Keywords
Photoinitiator; Photolysis; Diphenyliodonium salt; Cyclodextrin; Complex
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Photoreactive inclusion complex of aryliodonium salt encapsulated by methylated-β-cyclodextrin
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Publisher
Database: Elsevier - ScienceDirect
Journal: Journal of Photochemistry and Photobiology A: Chemistry - Volume 197, Issue 1, 10 June 2008, Pages 74–80
Authors
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Subjects
Physical Sciences and Engineering Chemical Engineering Bioengineering
Get Full-Text Now
Don't Miss Today's Special Offer
Price was $35.95
You save - $31
Price after discount Only $4.95
100% Money Back Guarantee
Full-text PDF Download
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Any Questions? feel free to contact us