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Irradiation of fluvastatin in water: Structure elucidation of photoproducts

Paper ID Volume ID Publish Year Pages File Format Full-Text
29274 44143 2007 8 PDF Available
Title
Irradiation of fluvastatin in water: Structure elucidation of photoproducts
Abstract

Fluvastatin is easily transformed in water by solar irradiation. One day-light exposure induces a complete degradation of the drug and formation of a mixture of products. Different chromatographic processes led to the isolation of dihydrobenzocarbazole, benzocarbazole, azonane-2,7-dione and spiro[4.4]azononane derivatives. Structures of photoproducts were elucidated by spectroscopic means. Photocyclization and photooxygenation are the main reactions involved in the formation of the observed products.

Keywords
Fluvastatin; Benzocarbazole derivatives; Lactam; Photocyclization; Photooxygenation
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Irradiation of fluvastatin in water: Structure elucidation of photoproducts
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Publisher
Database: Elsevier - ScienceDirect
Journal: Journal of Photochemistry and Photobiology A: Chemistry - Volume 189, Issues 2–3, 25 June 2007, Pages 264–271
Authors
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Subjects
Physical Sciences and Engineering Chemical Engineering Bioengineering
Get Full-Text Now
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Price was $35.95
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