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The role of spin states of dimethylgermylene in photoinduced processes

Paper ID Volume ID Publish Year Pages File Format Full-Text
31397 44759 2008 8 PDF Available
Title
The role of spin states of dimethylgermylene in photoinduced processes
Abstract

A joint consideration of the previous references and our own data has pointed to the possibility of the appearance of both S0 and T1 spin states of Me2Ge: in photoinduced processes. The absorption band at 430 nm should be attributed to the ground S0 state of Me2Ge:, and the absorption band at 480 nm should relate to the excited T1 state of Me2Ge:. In addition, the rate constants of addition to multiple bonds amount to 104–107 M−1 s−1 for the singlet particles and ∼1010 M−1 s−1 (diffusion controlled) for the triplet particles, respectively.

Keywords
Dimethylgermylene; Laser flash photolysis; Photochemistry; Reaction kinetics; UV-absorption spectra; Spectroscopy; Reactivity
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Publisher
Database: Elsevier - ScienceDirect
Journal: Journal of Photochemistry and Photobiology C: Photochemistry Reviews - Volume 9, Issue 4, December 2008, Pages 193–200
Authors
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Subjects
Physical Sciences and Engineering Chemical Engineering Bioengineering
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