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Spontaneous chiral crystallization of achiral materials and absolute asymmetric photochemical transformation using the chiral crystalline environment

Paper ID Volume ID Publish Year Pages File Format Full-Text
31420 44767 2006 14 PDF Available
Title
Spontaneous chiral crystallization of achiral materials and absolute asymmetric photochemical transformation using the chiral crystalline environment
Abstract

Asymmetric transformation using chiral crystals which are derived from chiral crystallization of achiral materials has been summarized. Solid-state photoreaction in the chiral crystal environment provides the reproducible absolute asymmetric synthesis via the cycloaddition reaction, hydrogen abstraction reaction, di-π-methane rearrangement, electrocyclization, and the bond-cleavage reaction. Furthermore, asymmetric syntheses using chiral crystals except solid-state photoreactions such as solid–gas reaction, catalytic asymmetric automultiplication, and the reaction in homogeneous conditions are also reviewed.

Keywords
Chiral crystallization; Absolute asymmetric synthesis; Spontaneous crystallization; Solid-state photoreaction; Chiral crystal
First Page Preview
Spontaneous chiral crystallization of achiral materials and absolute asymmetric photochemical transformation using the chiral crystalline environment
Publisher
Database: Elsevier - ScienceDirect
Journal: Journal of Photochemistry and Photobiology C: Photochemistry Reviews - Volume 7, Issue 4, December 2006, Pages 183–196
Authors
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Subjects
Physical Sciences and Engineering Chemical Engineering Bioengineering