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Excited-state double-proton transfer in a model DNA base pair: Resolution for stepwise and concerted mechanism controversy in the 7-azaindole dimer revealed by frequency- and time-resolved spectroscopy

Paper ID Volume ID Publish Year Pages File Format Full-Text
31428 44768 2008 11 PDF Available
Title
Excited-state double-proton transfer in a model DNA base pair: Resolution for stepwise and concerted mechanism controversy in the 7-azaindole dimer revealed by frequency- and time-resolved spectroscopy
Abstract

The excited-state double-proton transfer (ESDPT) reaction in the dual hydrogen-bonded 7-azaindole dimer (7AI2) in a supersonic jet expansion has been extensively studied with various laser spectroscopic methods and quantum chemistry calculations by many groups. This article reviews the results and discussions associated with stepwise and concerted mechanism controversy on ESDPT of 7AI2 together with the excited-state dynamics associated with ESDPT.

Keywords
Model DNA base pair; 7-azaindolole dimer; Excited-state double-proton transfer; Stepwise and concerted mechanisms; Frequency and time-resolved spectroscopy
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Excited-state double-proton transfer in a model DNA base pair: Resolution for stepwise and concerted mechanism controversy in the 7-azaindole dimer revealed by frequency- and time-resolved spectroscopy
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Publisher
Database: Elsevier - ScienceDirect
Journal: Journal of Photochemistry and Photobiology C: Photochemistry Reviews - Volume 9, Issue 2, June 2008, Pages 81–91
Authors
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Subjects
Physical Sciences and Engineering Chemical Engineering Bioengineering
Get Full-Text Now
Don't Miss Today's Special Offer
Price was $35.95
You save - $31
Price after discount Only $4.95
100% Money Back Guarantee
Full-text PDF Download
Online Support
Any Questions? feel free to contact us