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Influence of the state of Zn species over Zn-ZSM-5/ZSM-11 on the coupling effects of cofeeding n-butane with methanol

Paper ID Volume ID Publish Year Pages File Format Full-Text
38897 45796 2016 8 PDF Available
Title
Influence of the state of Zn species over Zn-ZSM-5/ZSM-11 on the coupling effects of cofeeding n-butane with methanol
Abstract

•Ion exchange method is beneficial for the formation of ZnOZn bridging species inside the micropore channel.•ZnOZn bridging species increase the promoting effect of cofeeding n-butane with methanol on aromatics selectivity.•Bulk ZnO particles promote the formation of C2C4 light alkane in cofeeding reaction.

Combination of the exothermic methanol aromatization with the endothermic n-butane aromatization provides a good way to meet the increasing demand for aromatics. Here, a series of Zn-ZSM-5/ZSM-11 catalysts were prepared with different introduction methods. The influence of location and state of Zn species on the coupling effects of cofeeding n-butane with methanol were investigated in detail. UV–vis, H2-TPR and XPS spectra were applied to reveal the state of the Zn species on different catalysts. Quantitative results of NH3-TPD and Pyridine-FTIR were provided to compare the acidity changes of the catalyst after Zn loading. Physical mixing method led to high portion of bulk ZnO particles outside the channel which could promote the formation of C2C4 light alkane in cofeeding reaction. Ion exchange and impregnation modes were beneficial for the formation of ZnOZn bridging species in the micropore channel. ZnOZn bridging species was found to increase the promoting effect of cofeeding n-butane with methanol on aromatics selectivity.

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Keywords
Zn state; Cofeeding; Methanol; n-Butane; Aromatization
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Influence of the state of Zn species over Zn-ZSM-5/ZSM-11 on the coupling effects of cofeeding n-butane with methanol
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Publisher
Database: Elsevier - ScienceDirect
Journal: Applied Catalysis A: General - Volume 519, 5 June 2016, Pages 48–55
Authors
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Subjects
Physical Sciences and Engineering Chemical Engineering Catalysis
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Don't Miss Today's Special Offer
Price was $35.95
You save - $31
Price after discount Only $4.95
100% Money Back Guarantee
Full-text PDF Download
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