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Catalytic hydrogen production through WGS or steam reforming of alcohols over Cu, Ni and Co catalysts

Paper ID Volume ID Publish Year Pages File Format Full-Text
38986 45800 2016 16 PDF Available
Title
Catalytic hydrogen production through WGS or steam reforming of alcohols over Cu, Ni and Co catalysts
Abstract

•Review of WGS and reforming of oxygenated hydrocarbons over Cu, Ni and Co catalysts.•Microstructure/interfacial chemistry of the supported metal catalysts upon interaction with respective reactant mixture.•Structural/morphological/redox properties and behavior toward deactivation under reaction conditions.

The work provides a review of water-gas shift and processes of reforming of oxygenated hydrocarbons, basically alcohols, employed for hydrogen production and focusing mainly on advances produced during last five years on catalysts of the base metals copper, nickel and cobalt. Particular attention is paid to analysis of the interplay between microstructure and interfacial chemistry of the supported metal catalysts and its interaction with the reaction mixture in each case. In this sense, the report basically covers how the interactions between the components of the catalysts in the various employed formulations and the presence of promoters affect to structural/morphological/chemical properties of the active metal in each case, their redox properties as well as processes involved in their deactivation under reaction conditions.

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Keywords
WGS; Reforming; Methanol; Ethanol; Biomass
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Catalytic hydrogen production through WGS or steam reforming of alcohols over Cu, Ni and Co catalysts
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Publisher
Database: Elsevier - ScienceDirect
Journal: Applied Catalysis A: General - Volume 518, 25 May 2016, Pages 2–17
Authors
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Subjects
Physical Sciences and Engineering Chemical Engineering Catalysis
Get Full-Text Now
Don't Miss Today's Special Offer
Price was $35.95
You save - $31
Price after discount Only $4.95
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