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Iron(III) porphyrin supported on S and N co-doped graphene quantum dot as an efficient photocatalyst for aerobic oxidation of alcohols under visible light irradiation

Paper ID Volume ID Publish Year Pages File Format Full-Text
39096 45806 2016 10 PDF Available
Title
Iron(III) porphyrin supported on S and N co-doped graphene quantum dot as an efficient photocatalyst for aerobic oxidation of alcohols under visible light irradiation
Abstract

•Synthesis of Fe(III)tetra(4-sulfonatophenyl)porphyrins (FeTSPP) supported on S and N co-doped graphene quantum dots (S, N: GQDs).•Noble metal free heterogeneous FeTSPP@S(GQDs), N: GQDs photocatalyst.•FeTSPP@S, N: GQDs photocatalyst with high selectivity and activity for aerobic oxidation of alcohols under visible light irradiations.•A recyclable and environmentally-friendly photocatalyst.

In this study, we report the synthesis and impressive performance of Fe(III)tetra(4-sulfonatophenyl)porphyrins (FeTSPP) supported on S and N co-doped graphene quantum dots (S, N: GQDs) as efficient, recyclable, and noble metal free heterogeneous photocatalyst for the selective aerobic oxidation of alcohols to the corresponding carbonyl compounds. It was found that FeTSPP@S, N: GQDs photocatalyst represents a novel chemical function for efficient visible light catalyzed aerobic alcohol oxidation with good conversions and selectivity in water as a green solvent at room temperature. We envision that FeTSPP@S, N: GQDs provide a promising candidate for the development of highly efficient, recyclable, and industrially applicable photocatalyst in fine chemical production with high activity.

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Keywords
Graphene quantum dots; Photocatalyst; Aerobic oxidation; Iron(III) porphyrin
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Iron(III) porphyrin supported on S and N co-doped graphene quantum dot as an efficient photocatalyst for aerobic oxidation of alcohols under visible light irradiation
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Publisher
Database: Elsevier - ScienceDirect
Journal: Applied Catalysis A: General - Volume 517, 5 May 2016, Pages 100–109
Authors
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Subjects
Physical Sciences and Engineering Chemical Engineering Catalysis
Get Full-Text Now
Don't Miss Today's Special Offer
Price was $35.95
You save - $31
Price after discount Only $4.95
100% Money Back Guarantee
Full-text PDF Download
Online Support
Any Questions? feel free to contact us