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Recoverable and reusable aluminium solvated species used as a homogeneous catalyst for biodiesel production from brown grease

Paper ID Volume ID Publish Year Pages File Format Full-Text
39155 45809 2015 8 PDF Available
Title
Recoverable and reusable aluminium solvated species used as a homogeneous catalyst for biodiesel production from brown grease
Abstract

•Brown grease was efficiently converted into biodiesel.•The reaction factors for catalysed direct esterification were optimised.•Recyclability and reusability of solvated aluminium species were tested.•The effect of water into direct esterification of FFAs was estimated.•The behaviour of AlCl3·6H2O into methanol was studied in ESI-MS.

Homogeneous aluminium species, obtained by dissolving AlCl3·6H2O into methanol, were characterised and tested as catalysts into the direct esterification of free fatty acids with methanol. The nature and the role of this catalyst was further investigated through ESI-MS and FTIR spectroscopy, by revealing an immediate exchange reaction between methanol and the water molecules originally bounded to the aluminium, producing a final mixed methanol-aquo-complex whose reactivity was found to be comparable to that of a methanolic solution of hydrogen chloride. Reaction conditions were optimised using the desirability function applied on the response surface methodology analysis of a Box–Behnken factorial design of experiments. By carrying out the reaction at 72 °C for 120 min and using a catalyst amount of 1.5% (mol of Al respect to fatty acids), almost 94% of the starting acids were converted. At the end of the reaction, a biphasic system was obtained in which the upper methanolic phase, which contained most of the starting catalyst, was separated from the heaviest phase, mainly composed of fatty acid methyl esters. Such a distribution not only allowed the biodiesel to be easily separated, but also the catalysts were efficiently recovered and reused for at least four times, determining a total TON greater than 200, without revealing any loss of its activity.

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Keywords
Al-solvated species; Biodiesel; Reusability; Water effect; Waste-derived fuels
First Page Preview
Recoverable and reusable aluminium solvated species used as a homogeneous catalyst for biodiesel production from brown grease
Publisher
Database: Elsevier - ScienceDirect
Journal: Applied Catalysis A: General - Volume 501, 25 July 2015, Pages 48–55
Authors
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Subjects
Physical Sciences and Engineering Chemical Engineering Catalysis