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Phosphine-functionalized ionic liquid-stabilized rhodium nanoparticles for selective hydrogenation of aromatic compounds

Paper ID Volume ID Publish Year Pages File Format Full-Text
39192 45812 2015 6 PDF Available
Title
Phosphine-functionalized ionic liquid-stabilized rhodium nanoparticles for selective hydrogenation of aromatic compounds
Abstract

•Highly regioselective hydrogenation of aromatic compounds.•Phosphine-functionalized ionic liquids stabilized rhodium nanoparticles as catalysts.•H2 and NaBH4 as reducing agents in the preparation of rhodium nanoparticles.•Mild reaction conditions and high recoverability of catalysts.

Phosphine-functionalized, ionic liquid-stabilized rhodium nanoparticles with an average size of about 3.5 nm are very active catalysts for the selective hydrogenation of aromatic compounds, including quinoline and its analogues, and aromatic nitro compounds. Their catalytic performance complements that of classic homogeneous and heterogeneous rhodium catalysis.

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Keywords
Selective hydrogenation; Nanoparticles; Ionic liquid; Quinoline; Rhodium
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Phosphine-functionalized ionic liquid-stabilized rhodium nanoparticles for selective hydrogenation of aromatic compounds
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Publisher
Database: Elsevier - ScienceDirect
Journal: Applied Catalysis A: General - Volume 499, 25 June 2015, Pages 118–123
Authors
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Subjects
Physical Sciences and Engineering Chemical Engineering Catalysis
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Price was $35.95
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