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Synthesis, characterization of MCM-41 with high vanadium content in the framework and its catalytic performance on selective oxidation of cyclohexane

Paper ID Volume ID Publish Year Pages File Format Full-Text
39748 45834 2014 6 PDF Available
Title
Synthesis, characterization of MCM-41 with high vanadium content in the framework and its catalytic performance on selective oxidation of cyclohexane
Abstract

•V-MCM-41 was prepared and the vanadium content was up to 8.1 wt.%.•The vanadium atoms were incorporated into the MCM-41 framework.•8.1 wt.% V-MCM-41 exhibited high selectivity for KA oil of 99.53%.•The mechanism of selective oxidation of cyclohexane was discussed.

V-MCM-41 with high content of vanadium in the framework was synthesized by using direct hydrothermal method under alkaline condition. Tartaric acid is the complexing reagent and cetyltrimethylammonium bromide is the structure-directing agent. The samples were characterized by X-ray fluorescence, X-ray diffraction, high-resolution transmission electron microscopy, N2 adsorption–desorption, Fourier-transform infrared spectroscopy, diffuse reflectance ultraviolet–visible spectroscopy and X-ray photoelectron spectroscopy techniques. The catalytic performance for the selective oxidation of cyclohexane was also examined. The results showed that the vanadium atoms were successfully introduced into the MCM-41 framework and the vanadium content reached up to 8.1 wt.%. Moreover, the V-MCM-41 samples possessed regular and stable structure with high specific surface area (692–939 m2 g−1), large pore diameter (3.6–4.6 nm) and large pore volume (0.86–0.95 cm3 g−1). The samples exhibited excellent catalytic performance of up to 22.57% cyclohexane conversion and 99.53% selectivity for cyclohexanone and cyclohexanol in the cyclohexane oxidation.

Graphical abstractThe possible reaction mechanism over the V-MCM-41 catalyst for the selective oxidation of cyclohexane.Figure optionsDownload full-size imageDownload high-quality image (79 K)Download as PowerPoint slide

Keywords
Heteroatom molecular sieve; Framework vanadium atoms; Cyclohexane selective oxidation; Cyclohexanol; Cyclohexanone
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Synthesis, characterization of MCM-41 with high vanadium content in the framework and its catalytic performance on selective oxidation of cyclohexane
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Publisher
Database: Elsevier - ScienceDirect
Journal: Applied Catalysis A: General - Volume 479, 5 June 2014, Pages 70–75
Authors
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Subjects
Physical Sciences and Engineering Chemical Engineering Catalysis
Get Full-Text Now
Don't Miss Today's Special Offer
Price was $35.95
You save - $31
Price after discount Only $4.95
100% Money Back Guarantee
Full-text PDF Download
Online Support
Any Questions? feel free to contact us