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Palladium-DABCO complex supported on γ-Fe2O3 magnetic nanoparticles: A new catalyst for CC bond formation via Mizoroki⬜Heck cross-coupling reaction

Paper ID Volume ID Publish Year Pages File Format Full-Text
39752 45834 2014 9 PDF Available
Title
Palladium-DABCO complex supported on γ-Fe2O3 magnetic nanoparticles: A new catalyst for CC bond formation via Mizoroki⬜Heck cross-coupling reaction
Abstract

⬢Palladium-DABCO complex supported on γ-Fe2O3 (Pd-DABCO-γ-Fe2O3) was synthesized.⬢Pd-DABCO-γ-Fe2O3 is a new phosphine-free palladium catalyst.⬢Pd-DABCO-γ-Fe2O3 was successfully applied in Mizoroki⬜Heck cross-coupling reaction.⬢Pd-DABCO-γ-Fe2O3 was isolated from the reaction mixture by magnetic decantation.

In this paper, palladium-DABCO complex supported on γ-Fe2O3 magnetic nanoparticles (Pd-DABCO-γ-Fe2O3) was synthesized and characterized by HRTEM, SEM, XRD, XPS, ICP, FT-IR, TGA, VSM and elemental analysis. The synthesized catalyst was successfully applied as a new magnetically recyclable heterogeneous catalyst in Mizoroki⬜Heck cross-coupling reaction of aryl halides with alkyl acrylates and styrene under solvent-free conditions.

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Keywords
Palladium; Magnetic nanoparticle; Heterogeneous catalyst; Mizoroki⬜Heck; DABCO
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Palladium-DABCO complex supported on γ-Fe2O3 magnetic nanoparticles: A new catalyst for CC bond formation via Mizoroki⬜Heck cross-coupling reaction
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Publisher
Database: Elsevier - ScienceDirect
Journal: Applied Catalysis A: General - Volume 479, 5 June 2014, Pages 112–120
Authors
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Subjects
Physical Sciences and Engineering Chemical Engineering Catalysis
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Price was $35.95
You save - $31
Price after discount Only $4.95
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Online Support
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