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Mono- and bi-metallic Au–Pd/TiO2 catalysts synthesized by one-step flame spray pyrolysis for liquid-phase hydrogenation of 1-heptyne

Paper ID Volume ID Publish Year Pages File Format Full-Text
40044 45843 2013 10 PDF Available
Title
Mono- and bi-metallic Au–Pd/TiO2 catalysts synthesized by one-step flame spray pyrolysis for liquid-phase hydrogenation of 1-heptyne
Abstract

•Au–Pd/TiO2 were synthesized by the single step flame spray pyrolysis.•FSP resulted in more uniform and smaller Au–Pd particles compared to IMP and DP.•Rate of 1-heptyne hydrogenation depended on Pd dispersion and location.•Selectivity to 1-heptene was greatly modified by the presence of Au–Pd alloy.

Monometallic Au/TiO2 and Pd/TiO2 and bimetallic Au–Pd/TiO2 nanoparticles were synthesized by flame spray pyrolysis (FSP) in a single step using palladium acetylacetonate, gold chloride trihydrate, and titanium butoxide as precursors dissolved in a xylene/acetonitrile mixture (70/30 vol%). For comparison purposes, bimetallic Au–Pd/TiO2 catalysts were also prepared by co-impregnation (IMP) and deposition–precipitation (DP) of Au and Pd on the FSP-derived TiO2. Based on the characterization results from X-ray diffraction (XRD), transmission electron spectroscopy-energy dispersive X-ray spectroscopy (TEM-EDX), X-ray photoelectron spectroscopy (XPS), N2 physisorption, and CO pulse chemisorption, Au–Pd alloy particles on the FSP-made AuPd/TiO2 were more uniform and smaller than those obtained by either DP or IMP methods. Both Au and Pd species (Au–Pd alloy particles) were presented on the surface of FSP-made catalysts. Smaller Pd/PdO particles with some pore blockages and formation of new pore structure of the TiO2 were seen on the catalysts prepared by DP and IMP. The rate of the liquid-phase hydrogenation of 1-heptyne depended on the Pd dispersion and the location of Pd particles. However, the selectivity to 1-heptene was greatly modified by the presence of Au–Pd alloy.

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Keywords
Flame spray pyrolysis; Au–Pd bimetallic catalysts; Liquid-phase hydrogenation; 1-Heptyne
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Mono- and bi-metallic Au–Pd/TiO2 catalysts synthesized by one-step flame spray pyrolysis for liquid-phase hydrogenation of 1-heptyne
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Publisher
Database: Elsevier - ScienceDirect
Journal: Applied Catalysis A: General - Volume 467, 2 October 2013, Pages 132–141
Authors
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Subjects
Physical Sciences and Engineering Chemical Engineering Catalysis
Get Full-Text Now
Don't Miss Today's Special Offer
Price was $35.95
You save - $31
Price after discount Only $4.95
100% Money Back Guarantee
Full-text PDF Download
Online Support
Any Questions? feel free to contact us