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Pd-nanoparticles supported onto functionalized poly(lactic acid)-based stereocomplexes for partial alkyne hydrogenation

Paper ID Volume ID Publish Year Pages File Format Full-Text
40159 45845 2014 7 PDF Available
Title
Pd-nanoparticles supported onto functionalized poly(lactic acid)-based stereocomplexes for partial alkyne hydrogenation
Abstract

•Simple synthesis of Pd-nanoparticles stabilized by functionalized poly(lactic acid)(PLA)-based stereocomplexes.•Partial hydrogenation of alkynes to alkenes under mild heterogeneous catalytic conditions.•Recyclable heterogenous (PLA)-based catalyst with low Pd leaching in the organic product phase.

Bipyridine-functionalized poly(lactic acid) (PLA)-based stereocomplexes were employed to stabilize Pd-nanoparticles (NPs). The well defined heterogeneous catalysts were suitable to catalyze the partial hydrogenation reaction (i.e. p(H2) = 3 bar, 25 and 60 °C) of phenylacetylene and diphenylacetylene in THF to give styrene and cis-stilbene with a chemoselectivity of 96% and 91%, respectively. Since the polymer support revealed stable under real catalytic conditions, stabilizing also efficiently the Pd-NPs in the course of the catalytic reaction, the heterogeneous catalytic system was easily recyclable. The catalytic activity as well as the chemoselectivity of the supported catalyst proved to be comparable in four consecutive catalytic cycles even by recovering the catalyst in air atmosphere after each cycle.

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Keywords
Polyesters; Stereocomplexes; Alkyne hydrogenation; Palladium nanoparticles
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Pd-nanoparticles supported onto functionalized poly(lactic acid)-based stereocomplexes for partial alkyne hydrogenation
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Publisher
Database: Elsevier - ScienceDirect
Journal: Applied Catalysis A: General - Volume 469, 17 January 2014, Pages 132–138
Authors
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Subjects
Physical Sciences and Engineering Chemical Engineering Catalysis
Get Full-Text Now
Don't Miss Today's Special Offer
Price was $35.95
You save - $31
Price after discount Only $4.95
100% Money Back Guarantee
Full-text PDF Download
Online Support
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