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Alcohol amination with heterogeneous ruthenium hydroxyapatite catalysts

Paper ID Volume ID Publish Year Pages File Format Full-Text
40167 45845 2014 7 PDF Available
Title
Alcohol amination with heterogeneous ruthenium hydroxyapatite catalysts
Abstract

•Intermolecular alcohol amination is accomplished with ruthenium on hydroxyapatite.•No base additives or pretreatments are required.•The catalyst is heterogeneous, as proven by hot filtration.•Both aromatic and aliphatic amines are alkylated with benzyl alcohol or 1-octanol.

The intermolecular amination of alcohols was performed with ruthenium (Ru3+) immobilized on a calcium hydroxyapatite support. No additional base additives were necessary, nor did the catalyst require base treatment prior to reaction. High conversions were obtained with different amine and alcohol reactants.

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Keywords
Amination; Ruthenium; Hydroxyapatite; N-alkylation; Borrowing hydrogen
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Alcohol amination with heterogeneous ruthenium hydroxyapatite catalysts
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Publisher
Database: Elsevier - ScienceDirect
Journal: Applied Catalysis A: General - Volume 469, 17 January 2014, Pages 191–197
Authors
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Subjects
Physical Sciences and Engineering Chemical Engineering Catalysis
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Price was $35.95
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