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Highly efficient divanadium(V) pre-catalyst for mild oxidation of liquid and gaseous alkanes

Paper ID Volume ID Publish Year Pages File Format Full-Text
40221 45846 2013 8 PDF Available
Title
Highly efficient divanadium(V) pre-catalyst for mild oxidation of liquid and gaseous alkanes
Abstract

•New binuclear V(V) complex bearing an NO2-donor Schiff base ligand is synthesized.•This compound is highly active catalyst precursor in the oxidation of alkanes by H2O2.•2-Pyrazinecarboxylic acid acts as an efficient co-catalyst.•High yields (up to 45% based on alkanes) and TONs (up to 7800) are achieved.•Oxidation proceeds via radical mechanism with participation of hydroxyl radicals.

A new binuclear oxovanadium(V) complex bearing an NO2-donor Schiff base ligand, [{VO(EtO)(EtOH)}2(1κ2O,κN:2κ2O,κN-L)]·2H2O (H4L = bis(2-hydroxybenzylidene)oxalohydrazonic acid) was prepared and fully characterized by IR, 1H NMR and electronic spectroscopies, elemental analysis and single crystal X-ray diffraction. In the presence of 2-pyrazinecarboxylic acid (PCA) or another acid promoter, this compound acts as a highly efficient pre-catalyst towards the oxidation of gaseous and liquid alkanes by aqueous H2O2 under mild conditions, in aqueous MeCN. Total yields of oxygenates up to 45% and overall turnover numbers up to 7.8 × 103 are achieved.

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Keywords
CH activation; Schiff bases; Hydrogen peroxide; Hydroxyl radical; 2-Pyrazinecarboxylic acid
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Highly efficient divanadium(V) pre-catalyst for mild oxidation of liquid and gaseous alkanes
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Publisher
Database: Elsevier - ScienceDirect
Journal: Applied Catalysis A: General - Volumes 460–461, 10 June 2013, Pages 82–89
Authors
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Subjects
Physical Sciences and Engineering Chemical Engineering Catalysis
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Price was $35.95
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