fulltext.study @t Gmail

Transesterification of acrylates by heterogeneous basic catalysis

Paper ID Volume ID Publish Year Pages File Format Full-Text
40228 45848 2013 8 PDF Available
Title
Transesterification of acrylates by heterogeneous basic catalysis
Abstract

•Solid basic catalysts are used in transesterification reaction of acrylates.•Solid basic catalysts proved to be active and selective.•Ca(NO3)2/γAl2O3 was shown to be the most selective and could be reused up to 4 cycles.•Transesterification reaction of acrylates would be favoured by weakest basic sites.

Different solid basic catalysts including CsF/αAl2O3, KF/αAl2O3, Ca(NO3)2/γAl2O3, NaNO3/γAl2O3, LiNO3/γAl2O3 were evaluated for the transesterification of ethyl acrylate by n-hexanol. All of them are active and selective in the transesterification reaction under mild conditions and without solvent, using a 1/1 molar ratio of reactants. Ca/γAl2O3 was shown to be the most selective of this set of catalysts and it could be recycled three times without lost of selectivity.

Graphical abstractFigure optionsDownload full-size imageDownload high-quality image (151 K)Download as PowerPoint slide

Keywords
Transesterification of acrylates; Solid bases; Supported alkalines oxides; Solvent-free reaction
First Page Preview
Transesterification of acrylates by heterogeneous basic catalysis
Get Full-Text Now
Don't Miss Today's Special Offer
Price was $35.95
You save - $31
Price after discount Only $4.95
100% Money Back Guarantee
Full-text PDF Download
Online Support
Any Questions? feel free to contact us
Publisher
Database: Elsevier - ScienceDirect
Journal: Applied Catalysis A: General - Volume 468, 5 November 2013, Pages 1–8
Authors
, , , ,
Subjects
Physical Sciences and Engineering Chemical Engineering Catalysis
Get Full-Text Now
Don't Miss Today's Special Offer
Price was $35.95
You save - $31
Price after discount Only $4.95
100% Money Back Guarantee
Full-text PDF Download
Online Support
Any Questions? feel free to contact us