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Influence of the synthesis conditions on the physicochemical properties and acidity of Al-MCM-41 as catalysts for the cyclohexanone oxime rearrangement

Paper ID Volume ID Publish Year Pages File Format Full-Text
40420 45852 2013 12 PDF Available
Title
Influence of the synthesis conditions on the physicochemical properties and acidity of Al-MCM-41 as catalysts for the cyclohexanone oxime rearrangement
Abstract

Al-containing mesoporous catalysts with MCM-41 structure and high surface area have been successfully prepared by direct hydrothermal synthesis. Various characterization techniques including XRD, N2 adsorption, ICP-OES, NMR, FT-IR and adsorption of pyridine coupled to FT-IR spectroscopy were employed. A detailed study about the relationships existing between the different synthesis parameters, the physico-chemical properties, the acid behavior and the catalytic performance is presented in this contribution. We have suggested that the active sites for the Beckmann rearrangement of cyclohexanone oxime are nest silanols (at structural defects) of very weak Brønsted acid character, which is associated with the introduction of Al into the mesoporous framework. In all the cases, employing soft reaction conditions, we have obtained selectivity to caprolactam of 100%. Finally, a Si/Al initial molar ratio of 20, a stirring of synthesis gel for 7 h and a hydrothermal treatment of 6 days seem to be the optimum synthesis conditions to obtain the highest framework Al incorporation, more abundant weak acid sites (silanol nests) and maximum yield for ξ-caprolactam.

Graphical abstractFigure optionsDownload full-size imageDownload high-quality image (76 K)Download as PowerPoint slideHighlights► Al-MCM-41 sieves have been successfully prepared by direct synthesis method. ► The incorporated Al depends on the hydrothermal synthesis time and stirring of gel. ► The presence of very weak acid nest silanols could be associated with framework Al. ► Beckmann rearrangement of CHO was carried out with selectivity to ξ-C of 100%. ► Acid silanol nests are proposed as the active sites for this reaction.

Keywords
Mesoporous materials; Al-MCM-41; Synthesis time; Gel stirring; ξ-Caprolactam
First Page Preview
Influence of the synthesis conditions on the physicochemical properties and acidity of Al-MCM-41 as catalysts for the cyclohexanone oxime rearrangement
Publisher
Database: Elsevier - ScienceDirect
Journal: Applied Catalysis A: General - Volume 453, 26 February 2013, Pages 391–402
Authors
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Subjects
Physical Sciences and Engineering Chemical Engineering Catalysis