fulltext.study @t Gmail

Preparation of Al, Ti, Zr-perfluoroheptanoate compounds and their use in ring opening polymerization

Paper ID Volume ID Publish Year Pages File Format Full-Text
41017 45874 2012 6 PDF Available
Title
Preparation of Al, Ti, Zr-perfluoroheptanoate compounds and their use in ring opening polymerization
Abstract

Aluminum, titanium and zirconium perfluoroheptanoate (PFH) were prepared by reaction of Al, Ti and Zr-alkoxides with perfluoroheptanoic acid (PFHA) in alcohol. All compounds were characterized by NMR spectroscopy, FTIR, MS and elemental analysis and used in polymerization of 3-glycidyloxypropyltrimethoxysilane (GPTS) in order to see their catalytic activity over epoxides. These catalysts were effective in ring opening of epoxide. Poly-GPTS was characterized by 1H, 13C NMR and gel permeation chromatography (GPC).

Graphical abstractFigure optionsDownload full-size imageDownload high-quality image (78 K)Download as PowerPoint slideHighlights► Preparation of new catalysts of aluminum, titanium and zirconium. ► Superiority of the catalysts in mild conditions with respect to the reported catalysts. ► Application of solvent free conditions in the polymerization reactions. ► Characterization of poly-GPTS by GPC and spectroscopic methods.

Keywords
Catalyst; Metal alkoxides; Perfluoroheptanoate; Ring-opening
First Page Preview
Preparation of Al, Ti, Zr-perfluoroheptanoate compounds and their use in ring opening polymerization
Get Full-Text Now
Don't Miss Today's Special Offer
Price was $35.95
You save - $31
Price after discount Only $4.95
100% Money Back Guarantee
Full-text PDF Download
Online Support
Any Questions? feel free to contact us
Publisher
Database: Elsevier - ScienceDirect
Journal: Applied Catalysis A: General - Volumes 423–424, 7 May 2012, Pages 205–210
Authors
, , ,
Subjects
Physical Sciences and Engineering Chemical Engineering Catalysis
Get Full-Text Now
Don't Miss Today's Special Offer
Price was $35.95
You save - $31
Price after discount Only $4.95
100% Money Back Guarantee
Full-text PDF Download
Online Support
Any Questions? feel free to contact us