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An atom-economic reaction for synthesis of 1-phenoxy-2-propanol over Al2O3/MgO

Paper ID Volume ID Publish Year Pages File Format Full-Text
41206 45880 2011 5 PDF Available
Title
An atom-economic reaction for synthesis of 1-phenoxy-2-propanol over Al2O3/MgO
Abstract

Al2O3/MgO materials with various Mg/Al molar ratios were prepared and characterized by XRD, FT-IR, SEM and BET analysis. These materials were used as catalysts for synthesis of 1-phenoxy-2-propanol (1-PhP) from phenol and propylene oxide as compared with some oxides, i.e. MgO, CaO, ZnO and Al2O3, etc. Al2O3/MgO with Al/Mg molar ratio of 1.5% exhibited outstanding catalytic performance with 98.2% conversion and 99.3% selectivity to 1-PhP at 120 °C for 5 h. This catalyst can be easily recovered and reused due to its heterogeneous catalytic nature.

Graphical abstractFigure optionsDownload full-size imageDownload high-quality image (81 K)Download as PowerPoint slideHighlights► Al2O3/MgO as an effective catalyst. ► Catalyst for atom-economic synthesis of 1-phenoxy-2-propanol. ► Al2O3 supported on promotes catalytic activity. ► The catalytic activity is ascribed to base–acid balance.

Keywords
Al2O3/MgO composite; Propylene oxide; 1-Phenoxy-2-propanol; Propanediol phenyl ether
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An atom-economic reaction for synthesis of 1-phenoxy-2-propanol over Al2O3/MgO
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Publisher
Database: Elsevier - ScienceDirect
Journal: Applied Catalysis A: General - Volume 408, Issues 1–2, 28 November 2011, Pages 125–129
Authors
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Subjects
Physical Sciences and Engineering Chemical Engineering Catalysis
Get Full-Text Now
Don't Miss Today's Special Offer
Price was $35.95
You save - $31
Price after discount Only $4.95
100% Money Back Guarantee
Full-text PDF Download
Online Support
Any Questions? feel free to contact us