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Epoxidation of alkenes and their derivatives over Ti-YNU-1

Paper ID Volume ID Publish Year Pages File Format Full-Text
41558 45893 2011 9 PDF Available
Title
Epoxidation of alkenes and their derivatives over Ti-YNU-1
Abstract

The catalytic properties of Ti-YNU-1 for the epoxidation of various alkenes and their derivatives have been investigated in detail, and further were made a comparison with those of Ti-Beta. The much higher efficiency of Ti-YNU-1 than Ti-Beta was observed in catalyzing the epoxidation of alkenes and their electron-rich analogues. Although it was less active in the epoxidation of α,β-unsaturated ketones, it showed much higher stability. In contrast, Ti leaching from the framework sites occurred to Ti-Beta, and the leaching degree increased with the carbon number of ketones. It was also shown that the catalytic conditions, including the Ti content in samples, H2O2/substrate ratio, reaction temperature and time, acid washing and catalyst amount, significantly influenced the activity, selectivity and H2O2 efficiency. Co-oxidation of different alkenes led to the activity and epoxide selectivity being different from those obtained in the oxidation of single olefin as a result of the differences in adsorption properties of substrates over various titanosilicates, which affected the diffusion of substrate molecules and accounted for the unique shape-selectivity of Ti-YNU-1.

Graphical abstractFigure optionsDownload full-size imageDownload high-quality image (144 K)Download as PowerPoint slideHighlights► Ti-YNU-1 are highly active and selective for epoxidation of alkenes and their derivatives. ► The catalytic properties of Ti-YNU-1 depend on the reaction conditions and the electronic and geometric features of substrates. ► Acid-treatment conditions greatly influence the structure and framework Ti content of Ti-YNU-1. ► The activity and selectivity of titanosilicates could be controlled by adding another type of alkene.

Keywords
Alkene; Epoxidation; Titanosilicate; Ti-YNU-1; Unsaturated ketone
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Epoxidation of alkenes and their derivatives over Ti-YNU-1
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Publisher
Database: Elsevier - ScienceDirect
Journal: Applied Catalysis A: General - Volume 401, Issues 1–2, 15 July 2011, Pages 37–45
Authors
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Subjects
Physical Sciences and Engineering Chemical Engineering Catalysis
Get Full-Text Now
Don't Miss Today's Special Offer
Price was $35.95
You save - $31
Price after discount Only $4.95
100% Money Back Guarantee
Full-text PDF Download
Online Support
Any Questions? feel free to contact us