fulltext.study @t Gmail

Immobilization of 1,5,7-triazabicyclo [4.4.0] dec-5-ene over mesoporous materials: An efficient catalyst for Michael-addition reactions under solvent-free condition

Paper ID Volume ID Publish Year Pages File Format Full-Text
41728 45897 2011 9 PDF Available
Title
Immobilization of 1,5,7-triazabicyclo [4.4.0] dec-5-ene over mesoporous materials: An efficient catalyst for Michael-addition reactions under solvent-free condition
Abstract

Immobilization of 1,5,7-triazabicyclo [4.4.0] dec-5-ene (TBD, a bicylic guanidine base) over mesoporous material like SBA-15 has been found to be an excellent catalyst for Michael-addition of β-nitro styrene with malonate. The reactions were performed under solvent-free condition at 373 K for 9 h. A wide variety of Michael donors and acceptors were investigated. Among them, high yield of Michael product was obtained for the reaction between p-Cl-nitrostyrene with dimethyl malonate.

Graphical abstractFigure optionsDownload full-size imageDownload high-quality image (104 K)Download as PowerPoint slide

Keywords
Mesoporous materials; 1,5,7-triazabicyclo [4.4.0] dec-5-ene; Michael-addition; β-nitro styrene and malonate
First Page Preview
Immobilization of 1,5,7-triazabicyclo [4.4.0] dec-5-ene over mesoporous materials: An efficient catalyst for Michael-addition reactions under solvent-free condition
Get Full-Text Now
Don't Miss Today's Special Offer
Price was $35.95
You save - $31
Price after discount Only $4.95
100% Money Back Guarantee
Full-text PDF Download
Online Support
Any Questions? feel free to contact us
Publisher
Database: Elsevier - ScienceDirect
Journal: Applied Catalysis A: General - Volume 397, Issues 1–2, 30 April 2011, Pages 250–258
Authors
, ,
Subjects
Physical Sciences and Engineering Chemical Engineering Catalysis
Get Full-Text Now
Don't Miss Today's Special Offer
Price was $35.95
You save - $31
Price after discount Only $4.95
100% Money Back Guarantee
Full-text PDF Download
Online Support
Any Questions? feel free to contact us