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Understanding the role of halogen-containing ionic liquids in the hydrolysis of cellobiose catalyzed by acid resins

Paper ID Volume ID Publish Year Pages File Format Full-Text
41805 45900 2010 6 PDF Available
Title
Understanding the role of halogen-containing ionic liquids in the hydrolysis of cellobiose catalyzed by acid resins
Abstract

In the hydrolysis of cellobiose to glucose, the addition of 1-butyl-3-methylimidazolium chloride (BmimCl) ionic liquid (IL) enhanced the catalytic activity of Nafion® NR50 substantially. Similar results were observed with 1-butyl-2,3-dimethylimidazolium chloride, 1-ethyl-3-methylimidazolium chloride, 1-allyl-3-methylimidazolium chloride, and 1-butyl-3-methylimidazolium bromide and iodide, but not acetate. The glucose yield was the highest when the amount of BmimCl added equalled the number of protons available in the resin catalyst, but further addition of BmimCl did not lead to substantial changes in the glucose yield. The extent of activity enhancement did not correlate well with the extent of swelling of the Nafion® NR50 resin, but correlated well with the pH change of the reaction mixture due to the presence of ILs. It is believed that the principal contributor to the effect of ILs is displacement of the protons of the sulfonate groups in the resin by ion-exchange with imidazolium ions, and these released protons are the catalyst for the hydrolysis reaction. For the IL with acetate as the anion, the released protons associate with acetate to form acetic acid, which is a weak acid and has low hydrolysis activity.

Graphical abstractFigure optionsDownload full-size imageDownload high-quality image (88 K)Download as PowerPoint slideResearch highlights▶ Addition of halogen-containing ionic liquids enhances the activity of acid resins. ▶ The extent of activity enhancement correlates with the pH change of the solution. ▶ Displacement of the resin's protons with imidazolium ions occurs during the reaction. ▶ Protons released by ion-exchange are the catalyst for the hydrolysis reaction.

Keywords
Ionic liquids; Halogen anions; Acid resins; Cellobiose; Hydrolysis
First Page Preview
Understanding the role of halogen-containing ionic liquids in the hydrolysis of cellobiose catalyzed by acid resins
Publisher
Database: Elsevier - ScienceDirect
Journal: Applied Catalysis A: General - Volume 387, Issues 1–2, 20 October 2010, Pages 209–214
Authors
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Subjects
Physical Sciences and Engineering Chemical Engineering Catalysis