fulltext.study @t Gmail

Telomerisation of 1,3-butadiene with glycerol under aqueous biphasic conditions: Influence of the reaction conditions on the products distribution

Paper ID Volume ID Publish Year Pages File Format Full-Text
42082 45910 2010 9 PDF Available
Title
Telomerisation of 1,3-butadiene with glycerol under aqueous biphasic conditions: Influence of the reaction conditions on the products distribution
Abstract

The palladium-catalyzed telomerisation of butadiene with glycerol has been studied under aqueous biphasic conditions both in the presence of a liquid phase of butadiene and under gaseous atmosphere of butadiene. In this last case, gaseous butadiene was continuously added during the whole reaction time keeping constant its pressure. Most of the products formed have been fully characterized. The influence of various experimental parameters has been checked with the aim to obtain high activities and selectivities either into mono-, di- or tritelomers.

Graphical abstractThe telomerisation of butadiene with glycerol catalyzed by palladium under aqueous biphasic conditions has been investigated in detail as well as under gaseous atmosphere of butadiene than in the presence of a liquid phase of butadiene. The influence of various experimental parameters such as the nature of the hydrosoluble ligand, the nature of the base and its amount, the amount of butadiene or water, …, has been checked with the aim to obtain high activities and selectivities either into mono-, di- or tritelomers.Figure optionsDownload full-size imageDownload high-quality image (68 K)Download as PowerPoint slide

Keywords
Telomerisation; Glycerol; Butadiene; Palladium catalysis; Octadienyl ethers
First Page Preview
Telomerisation of 1,3-butadiene with glycerol under aqueous biphasic conditions: Influence of the reaction conditions on the products distribution
Get Full-Text Now
Don't Miss Today's Special Offer
Price was $35.95
You save - $31
Price after discount Only $4.95
100% Money Back Guarantee
Full-text PDF Download
Online Support
Any Questions? feel free to contact us
Publisher
Database: Elsevier - ScienceDirect
Journal: Applied Catalysis A: General - Volume 382, Issue 2, 15 July 2010, Pages 181–189
Authors
, , , , , ,
Subjects
Physical Sciences and Engineering Chemical Engineering Catalysis
Get Full-Text Now
Don't Miss Today's Special Offer
Price was $35.95
You save - $31
Price after discount Only $4.95
100% Money Back Guarantee
Full-text PDF Download
Online Support
Any Questions? feel free to contact us