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Further support for the two-mechanisms hypothesis of Fischer–Tropsch synthesis

Paper ID Volume ID Publish Year Pages File Format Full-Text
42144 45912 2010 6 PDF Available
Title
Further support for the two-mechanisms hypothesis of Fischer–Tropsch synthesis
Abstract

The recently proposed hypothesis of two incompatible mechanisms of chain growth based on CH2- and CO-insertion is furthermore supported by a detailed interpretation of the 13CH2N2 co-feeding experiments of Maitlis and co-workers and of the selectivity of branched hydrocarbons.The carbon number distribution is discussed considering in particular the role of readsorption and incorporation of 1-alkenes and its subsequent chain growth.

Graphical abstractThe hypothesis of two incompatible mechanisms of chain growth finds strong support by detailed interpretation of CH2N2 co-feeding experiments and the selectivity of branched hydrocarbons. Deviations of the carbon number distribution from the strict superposition of two ASF distributions are interpreted by the subsequent chain growth of readsorbed 1-alkenes via the mechanism characterized by CH2-insertion.Figure optionsDownload full-size imageDownload high-quality image (85 K)Download as PowerPoint slide

Keywords
Fischer–Tropsch synthesis; Mechanisms
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Further support for the two-mechanisms hypothesis of Fischer–Tropsch synthesis
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Publisher
Database: Elsevier - ScienceDirect
Journal: Applied Catalysis A: General - Volume 374, Issues 1–2, 1 February 2010, Pages 120–125
Authors
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Subjects
Physical Sciences and Engineering Chemical Engineering Catalysis
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