fulltext.study @t Gmail

Catalytic oxidation of tetralin by biologically active copper and palladium complexes

Paper ID Volume ID Publish Year Pages File Format Full-Text
42303 45920 2009 5 PDF Available
Title
Catalytic oxidation of tetralin by biologically active copper and palladium complexes
Abstract

The biologically active complexes [Cu(CTZ)4]Cl2 (1), [Cu(CTZ)2Cl2]2 (2) and Pd(CTZ)2Cl2 (3) were evaluated as catalyst precursors for the homogeneous oxidation of tetralin under aerobic conditions. The catalytic reaction was carried out using the following conditions determined for [Cu(CTZ)4]Cl2: T = 373 K, Pair = 35.0 atm, substrate/catalyst ratio = 700, reaction time = 9 h. These complexes were effective catalyst precursors for the selective oxidation of tetralin to α-tetralone and α-tetralol. Copper complexes 1 and 2 performed better than the palladium complex both in conversion (over 50%) and selectivity towards the production of α-tetralone (one/ol = 3).

Graphical abstractThe biologically active complexes [Cu(CTZ)4]Cl2, [Cu(CTZ)2Cl2]2 and Pd(CTZ)2Cl2 were evaluated as catalyst precursors for the homogeneous oxidation of tetralin under aerobic conditions. Copper complexes were found to perform better than the palladium complexes under the studied conditions, leading to higher conversions and selectivity towards α-tetralone.Figure optionsDownload full-size imageDownload as PowerPoint slide

Keywords
Oxidation; Tetralin; Copper(II) complexes; Palladium(II) complexes
First Page Preview
Catalytic oxidation of tetralin by biologically active copper and palladium complexes
Get Full-Text Now
Don't Miss Today's Special Offer
Price was $35.95
You save - $31
Price after discount Only $4.95
100% Money Back Guarantee
Full-text PDF Download
Online Support
Any Questions? feel free to contact us
Publisher
Database: Elsevier - ScienceDirect
Journal: Applied Catalysis A: General - Volume 363, Issues 1–2, 1 July 2009, Pages 27–31
Authors
, , , , , , ,
Subjects
Physical Sciences and Engineering Chemical Engineering Catalysis
Get Full-Text Now
Don't Miss Today's Special Offer
Price was $35.95
You save - $31
Price after discount Only $4.95
100% Money Back Guarantee
Full-text PDF Download
Online Support
Any Questions? feel free to contact us