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Heterogenized copper catalysts for the amination of arylhalide: Synthesis, characterization and catalytic applications

Paper ID Volume ID Publish Year Pages File Format Full-Text
42370 45922 2010 9 PDF Available
Title
Heterogenized copper catalysts for the amination of arylhalide: Synthesis, characterization and catalytic applications
Abstract

This research investigated the synthesis, characterization and catalytic activity of heterogenized copper complexes for the selective amination of aryl halides. Amination reactions using homogeneous copper catalyst systems are not generally selective and it is also difficult to recover the catalyst from the homogeneous system for recycling. To overcome these difficulties, our efforts were directed towards the development of cheaper heterogeneous catalyst systems, which can be easily recovered and recycled. Heterogenized analogs of the homogenous Cu complexes were prepared using two methods: (a) encapsulation of copper complexes in zeolite-Y and (b) tethering of copper complexes on various supports like zeolite-Y, silica, charcoal, or clay. The encapsulated and tethered copper catalysts on zeolite-Y were characterized using EPR, Diffused reflectance UV–vis, XRD, IAS, ICPES, SEM, and TEM. The results confirmed that the copper complexes were truly heterogenized in zeolite-Y support. Encapsulated and tethered copper complexes were tested for amination of aryl iodide. The effects of various reaction parameters were examined using tethered Cu(Phen)(PPh3)Br-PTA-Y catalyst to determine optimum conditions. A recycle study of encapsulated and tethered Cu catalyst was carried out to test their robustness for possible commercial exploitation.

Graphical abstractA heterogenized copper catalyst for selective amination to diphenylamine has been described. The Na–Y encapsulated copper complex catalyst for amination of aryl iodide showed shape-selective formation of diphenylamine. The catalyst could be recycled five times with a cumulative TON of ∼200.Figure optionsDownload full-size imageDownload as PowerPoint slide

Keywords
C–N coupling; Heterogeneous catalysis; Amination; Mesoporous materials; Copper
First Page Preview
Heterogenized copper catalysts for the amination of arylhalide: Synthesis, characterization and catalytic applications
Publisher
Database: Elsevier - ScienceDirect
Journal: Applied Catalysis A: General - Volume 372, Issue 1, 5 January 2010, Pages 73–81
Authors
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Subjects
Physical Sciences and Engineering Chemical Engineering Catalysis