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Heterolytic activation of hydrogen gas: New evidence for Spencer–Yu hypothesis!

Paper ID Volume ID Publish Year Pages File Format Full-Text
42988 45950 2008 4 PDF Available
Title
Heterolytic activation of hydrogen gas: New evidence for Spencer–Yu hypothesis!
Abstract

Hydrogenolysis or deuterogenolysis of organolithium compounds is described for the first time under heterogeneous catalysis. This work establishes that the carbon–lithium bond can undergo a facile reduction reaction when catalyzed by palladium or platinum catalysts and provides strong evidence for the existence of Pdδ−–Hδ+ species.

Graphical abstractHydrogenolysis of organolithium reagents is described under heterogeneous catalysis in the presence of Pd0. This approach gives details about the H–H bond polarization in the presence of transition metal catalysts.Figure optionsDownload full-size imageDownload as PowerPoint slide

Keywords
Deuterium; Hydrogenolysis; Heterogeneous catalysis; Organolithium; Palladium
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Heterolytic activation of hydrogen gas: New evidence for Spencer–Yu hypothesis!
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Publisher
Database: Elsevier - ScienceDirect
Journal: Applied Catalysis A: General - Volume 346, Issues 1–2, 31 August 2008, Pages 86–89
Authors
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Subjects
Physical Sciences and Engineering Chemical Engineering Catalysis
Get Full-Text Now
Don't Miss Today's Special Offer
Price was $35.95
You save - $31
Price after discount Only $4.95
100% Money Back Guarantee
Full-text PDF Download
Online Support
Any Questions? feel free to contact us